Mass spectrometric characterization of isomeric terpenoic acids from the oxidation of α‐pinene, β‐pinene, d‐limonene, and Δ3‐carene in fine forest aerosol
Identifieur interne : 000007 ( France/Analysis ); précédent : 000006; suivant : 000008Mass spectrometric characterization of isomeric terpenoic acids from the oxidation of α‐pinene, β‐pinene, d‐limonene, and Δ3‐carene in fine forest aerosol
Auteurs : Farhat Yasmeen [Belgique, France] ; Rafal Szmigielski [Belgique, Pologne] ; Reinhilde Vermeylen [Belgique] ; Yadian G Mez-González [Belgique] ; Jason D. Surratt [États-Unis] ; Arthur W. H. Chan [États-Unis] ; John H. Seinfeld [États-Unis] ; Willy Maenhaut [Belgique] ; Magda Claeys [Belgique]Source :
- Journal of Mass Spectrometry [ 1076-5174 ] ; 2011-04.
English descriptors
- KwdEn :
Abstract
In this study, we present liquid chromatographic and mass spectral data for predominant terpenoic acids formed through oxidation of α‐pinene, β‐pinene, d‐limonene, and Δ3‐carene that occur in fine forest aerosol from K‐puszta, Hungary, a rural site with coniferous vegetation. Characterization of these secondary organic aerosol tracers in fine ambient aerosol is important because it allows one to gain information on monoterpene precursors and source processes such as oxidation and aging processes. The mass spectral data were obtained using electrospray ionization in the negative ion mode, accurate mass measurements, and linear ion trap tandem mass spectrometric experiments. Emphasis is given to the mass spectrometric differentiation of isobaric terpenoic acids, such as, e.g. the molecular weight (MW) 186 terpenoic acids, cis‐pinic, cis‐caric, homoterpenylic, ketolimononic, and limonic acids. Other targeted isobaric terpenoic acids are the MW 184 terpenoic acids, cis‐pinonic and cis‐caronic acids, and the MW 204 tricarboxylic acids, 3‐methyl‐1,2,3‐butanetricarboxylic and 3‐carboxyheptanedioic acids. Fragmentation pathways are proposed to provide a rational explanation for the observed isomeric differences and/or to support the suggested tentative structures. For the completeness of the data set, data obtained for recently reported lactone‐containing terpenoic acids (i.e. terpenylic and terebic acids), related or isobaric compounds (i.e. norpinic acid, diaterpenylic acid acetate, and unknown MW 188 compounds) are also included, the rationale being that other groups working on this topic could use this data compilation as a reference. Copyright © 2011 John Wiley & Sons, Ltd.
Url:
DOI: 10.1002/jms.1911
Affiliations:
- Belgique, France, Pologne, États-Unis
- Caroline du Nord, Provence-Alpes-Côte d'Azur, Province d'Anvers, Province de Flandre-Orientale, Région flamande
- Anvers, Chapel Hill (Caroline du Nord), Gand, Nice
- Université d'Anvers, Université de Caroline du Nord à Chapel Hill, Université de Gand
Links toward previous steps (curation, corpus...)
- to stream Main, to step Corpus: 000691
- to stream Main, to step Curation: 000691
- to stream Main, to step Exploration: 000038
- to stream France, to step Extraction: 000007
Links to Exploration step
ISTEX:2E7DC6F7F66D79FF4FFD8C32B9F78A48EEE0687BLe document en format XML
<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">Mass spectrometric characterization of isomeric terpenoic acids from the oxidation of α‐pinene, β‐pinene, d‐limonene, and Δ3‐carene in fine forest aerosol</title><author><name sortKey="Yasmeen, Farhat" sort="Yasmeen, Farhat" uniqKey="Yasmeen F" first="Farhat" last="Yasmeen">Farhat Yasmeen</name></author><author><name sortKey="Szmigielski, Rafal" sort="Szmigielski, Rafal" uniqKey="Szmigielski R" first="Rafal" last="Szmigielski">Rafal Szmigielski</name></author><author><name sortKey="Vermeylen, Reinhilde" sort="Vermeylen, Reinhilde" uniqKey="Vermeylen R" first="Reinhilde" last="Vermeylen">Reinhilde Vermeylen</name></author><author><name sortKey="G Mez Onzalez, Yadian" sort="G Mez Onzalez, Yadian" uniqKey="G Mez Onzalez Y" first="Yadian" last="G Mez-González">Yadian G Mez-González</name></author><author><name sortKey="Surratt, Jason D" sort="Surratt, Jason D" uniqKey="Surratt J" first="Jason D." last="Surratt">Jason D. Surratt</name></author><author><name sortKey="Chan, Arthur W H" sort="Chan, Arthur W H" uniqKey="Chan A" first="Arthur W. H." last="Chan">Arthur W. H. Chan</name></author><author><name sortKey="Seinfeld, John H" sort="Seinfeld, John H" uniqKey="Seinfeld J" first="John H." last="Seinfeld">John H. Seinfeld</name></author><author><name sortKey="Maenhaut, Willy" sort="Maenhaut, Willy" uniqKey="Maenhaut W" first="Willy" last="Maenhaut">Willy Maenhaut</name></author><author><name sortKey="Claeys, Magda" sort="Claeys, Magda" uniqKey="Claeys M" first="Magda" last="Claeys">Magda Claeys</name></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:2E7DC6F7F66D79FF4FFD8C32B9F78A48EEE0687B</idno><date when="2011" year="2011">2011</date><idno type="doi">10.1002/jms.1911</idno><idno type="url">https://api.istex.fr/document/2E7DC6F7F66D79FF4FFD8C32B9F78A48EEE0687B/fulltext/pdf</idno><idno type="wicri:Area/Main/Corpus">000691</idno><idno type="wicri:Area/Main/Curation">000691</idno><idno type="wicri:Area/Main/Exploration">000038</idno><idno type="wicri:explorRef" wicri:stream="Main" wicri:step="Exploration">000038</idno><idno type="wicri:Area/France/Extraction">000007</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">Mass spectrometric characterization of isomeric terpenoic acids from the oxidation of α‐pinene, β‐pinene, d‐limonene, and Δ3‐carene in fine forest aerosol</title><author><name sortKey="Yasmeen, Farhat" sort="Yasmeen, Farhat" uniqKey="Yasmeen F" first="Farhat" last="Yasmeen">Farhat Yasmeen</name><affiliation wicri:level="4"><country xml:lang="fr">Belgique</country><wicri:regionArea>Department of Pharmaceutical Sciences, University of Antwerp, BE‐2610 Antwerp</wicri:regionArea><orgName type="university">Université d'Anvers</orgName><placeName><settlement type="city">Anvers</settlement><region>Région flamande</region><region type="district" nuts="2">Province d'Anvers</region></placeName></affiliation><affiliation wicri:level="3"><country xml:lang="fr">France</country><wicri:regionArea>Laboratoire de Radiochimie, Sciences Analytiques et Environnement (LRSAE), Institut de Chimie de Nice (CNRS, FR 3037), Faculty of Sciences, University of Nice Sophia‐Antipolis, F‐06108 Nice</wicri:regionArea><placeName><region type="region" nuts="2">Provence-Alpes-Côte d'Azur</region><settlement type="city">Nice</settlement></placeName></affiliation></author><author><name sortKey="Szmigielski, Rafal" sort="Szmigielski, Rafal" uniqKey="Szmigielski R" first="Rafal" last="Szmigielski">Rafal Szmigielski</name><affiliation wicri:level="4"><country xml:lang="fr">Belgique</country><wicri:regionArea>Department of Pharmaceutical Sciences, University of Antwerp, BE‐2610 Antwerp</wicri:regionArea><orgName type="university">Université d'Anvers</orgName><placeName><settlement type="city">Anvers</settlement><region>Région flamande</region><region type="district" nuts="2">Province d'Anvers</region></placeName></affiliation><affiliation wicri:level="1"><country xml:lang="fr">Pologne</country><wicri:regionArea>Current Address: Institute of Physical Chemistry of the Polish Academy of Sciences, 01‐224, Warsaw</wicri:regionArea><wicri:noRegion>Warsaw</wicri:noRegion></affiliation></author><author><name sortKey="Vermeylen, Reinhilde" sort="Vermeylen, Reinhilde" uniqKey="Vermeylen R" first="Reinhilde" last="Vermeylen">Reinhilde Vermeylen</name><affiliation wicri:level="4"><country xml:lang="fr">Belgique</country><wicri:regionArea>Department of Pharmaceutical Sciences, University of Antwerp, BE‐2610 Antwerp</wicri:regionArea><orgName type="university">Université d'Anvers</orgName><placeName><settlement type="city">Anvers</settlement><region>Région flamande</region><region type="district" nuts="2">Province d'Anvers</region></placeName></affiliation></author><author><name sortKey="G Mez Onzalez, Yadian" sort="G Mez Onzalez, Yadian" uniqKey="G Mez Onzalez Y" first="Yadian" last="G Mez-González">Yadian G Mez-González</name><affiliation wicri:level="4"><country xml:lang="fr">Belgique</country><wicri:regionArea>Department of Pharmaceutical Sciences, University of Antwerp, BE‐2610 Antwerp</wicri:regionArea><orgName type="university">Université d'Anvers</orgName><placeName><settlement type="city">Anvers</settlement><region>Région flamande</region><region type="district" nuts="2">Province d'Anvers</region></placeName></affiliation></author><author><name sortKey="Surratt, Jason D" sort="Surratt, Jason D" uniqKey="Surratt J" first="Jason D." last="Surratt">Jason D. Surratt</name><affiliation wicri:level="1"><country xml:lang="fr">États-Unis</country><wicri:regionArea>Department of Chemistry, California Institute of Technology (Caltech), Pasadena, California 91125</wicri:regionArea><wicri:noRegion>California 91125</wicri:noRegion></affiliation><affiliation wicri:level="4"><country xml:lang="fr" wicri:curation="lc">États-Unis</country><wicri:regionArea>Current Address: Department of Environmental Sciences and Engineering, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina 27599</wicri:regionArea><orgName type="university">Université de Caroline du Nord à Chapel Hill</orgName><placeName><settlement type="city">Chapel Hill (Caroline du Nord)</settlement><region type="state">Caroline du Nord</region></placeName></affiliation></author><author><name sortKey="Chan, Arthur W H" sort="Chan, Arthur W H" uniqKey="Chan A" first="Arthur W. H." last="Chan">Arthur W. H. Chan</name><affiliation wicri:level="1"><country xml:lang="fr">États-Unis</country><wicri:regionArea>Department of Chemical Engineering, California Institute of Technology (Caltech), Pasadena, California 91125</wicri:regionArea><wicri:noRegion>California 91125</wicri:noRegion></affiliation><affiliation wicri:level="1"><country xml:lang="fr" wicri:curation="lc">États-Unis</country><wicri:regionArea>Current Address: Department of Environmental Science, Policy and Management, University of California at Berkeley, Berkeley, California 94720</wicri:regionArea><wicri:noRegion>California 94720</wicri:noRegion></affiliation></author><author><name sortKey="Seinfeld, John H" sort="Seinfeld, John H" uniqKey="Seinfeld J" first="John H." last="Seinfeld">John H. Seinfeld</name><affiliation wicri:level="1"><country xml:lang="fr">États-Unis</country><wicri:regionArea>Department of Chemical Engineering, California Institute of Technology (Caltech), Pasadena, California 91125</wicri:regionArea><wicri:noRegion>California 91125</wicri:noRegion></affiliation><affiliation wicri:level="1"><country xml:lang="fr">États-Unis</country><wicri:regionArea>Department of Environmental Science and Engineering, California Institute of Technology (Caltech), Pasadena, California 91125</wicri:regionArea><wicri:noRegion>California 91125</wicri:noRegion></affiliation></author><author><name sortKey="Maenhaut, Willy" sort="Maenhaut, Willy" uniqKey="Maenhaut W" first="Willy" last="Maenhaut">Willy Maenhaut</name><affiliation wicri:level="4"><country xml:lang="fr">Belgique</country><wicri:regionArea>Department of Analytical Chemistry, Institute for Nuclear Sciences, Ghent University, BE‐9000 Gent</wicri:regionArea><orgName type="university">Université de Gand</orgName><placeName><settlement type="city">Gand</settlement><region>Région flamande</region><region type="district" nuts="2">Province de Flandre-Orientale</region></placeName></affiliation></author><author><name sortKey="Claeys, Magda" sort="Claeys, Magda" uniqKey="Claeys M" first="Magda" last="Claeys">Magda Claeys</name><affiliation wicri:level="4"><country xml:lang="fr">Belgique</country><wicri:regionArea>Department of Pharmaceutical Sciences, University of Antwerp, BE‐2610 Antwerp</wicri:regionArea><orgName type="university">Université d'Anvers</orgName><placeName><settlement type="city">Anvers</settlement><region>Région flamande</region><region type="district" nuts="2">Province d'Anvers</region></placeName></affiliation></author></analytic><monogr></monogr><series><title level="j">Journal of Mass Spectrometry</title><title level="j" type="abbrev">J. Mass Spectrom.</title><idno type="ISSN">1076-5174</idno><idno type="eISSN">1096-9888</idno><imprint><publisher>John Wiley & Sons, Ltd.</publisher><pubPlace>Chichester, UK</pubPlace><date type="published" when="2011-04">2011-04</date><biblScope unit="volume">46</biblScope><biblScope unit="issue">4</biblScope><biblScope unit="page" from="425">425</biblScope><biblScope unit="page" to="442">442</biblScope></imprint><idno type="ISSN">1076-5174</idno></series><idno type="istex">2E7DC6F7F66D79FF4FFD8C32B9F78A48EEE0687B</idno><idno type="DOI">10.1002/jms.1911</idno><idno type="ArticleID">JMS1911</idno></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">1076-5174</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>ambient aerosol</term><term>electrospray ionization</term><term>fine particulate matter</term><term>linear ion trap</term><term>secondary organic aerosol</term></keywords></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract">In this study, we present liquid chromatographic and mass spectral data for predominant terpenoic acids formed through oxidation of α‐pinene, β‐pinene, d‐limonene, and Δ3‐carene that occur in fine forest aerosol from K‐puszta, Hungary, a rural site with coniferous vegetation. Characterization of these secondary organic aerosol tracers in fine ambient aerosol is important because it allows one to gain information on monoterpene precursors and source processes such as oxidation and aging processes. The mass spectral data were obtained using electrospray ionization in the negative ion mode, accurate mass measurements, and linear ion trap tandem mass spectrometric experiments. Emphasis is given to the mass spectrometric differentiation of isobaric terpenoic acids, such as, e.g. the molecular weight (MW) 186 terpenoic acids, cis‐pinic, cis‐caric, homoterpenylic, ketolimononic, and limonic acids. Other targeted isobaric terpenoic acids are the MW 184 terpenoic acids, cis‐pinonic and cis‐caronic acids, and the MW 204 tricarboxylic acids, 3‐methyl‐1,2,3‐butanetricarboxylic and 3‐carboxyheptanedioic acids. Fragmentation pathways are proposed to provide a rational explanation for the observed isomeric differences and/or to support the suggested tentative structures. For the completeness of the data set, data obtained for recently reported lactone‐containing terpenoic acids (i.e. terpenylic and terebic acids), related or isobaric compounds (i.e. norpinic acid, diaterpenylic acid acetate, and unknown MW 188 compounds) are also included, the rationale being that other groups working on this topic could use this data compilation as a reference. Copyright © 2011 John Wiley & Sons, Ltd.</div></front></TEI><affiliations><list><country><li>Belgique</li><li>France</li><li>Pologne</li><li>États-Unis</li></country><region><li>Caroline du Nord</li><li>Provence-Alpes-Côte d'Azur</li><li>Province d'Anvers</li><li>Province de Flandre-Orientale</li><li>Région flamande</li></region><settlement><li>Anvers</li><li>Chapel Hill (Caroline du Nord)</li><li>Gand</li><li>Nice</li></settlement><orgName><li>Université d'Anvers</li><li>Université de Caroline du Nord à Chapel Hill</li><li>Université de Gand</li></orgName></list><tree><country name="Belgique"><region name="Région flamande"><name sortKey="Yasmeen, Farhat" sort="Yasmeen, Farhat" uniqKey="Yasmeen F" first="Farhat" last="Yasmeen">Farhat Yasmeen</name></region><name sortKey="Claeys, Magda" sort="Claeys, Magda" uniqKey="Claeys M" first="Magda" last="Claeys">Magda Claeys</name><name sortKey="G Mez Onzalez, Yadian" sort="G Mez Onzalez, Yadian" uniqKey="G Mez Onzalez Y" first="Yadian" last="G Mez-González">Yadian G Mez-González</name><name sortKey="Maenhaut, Willy" sort="Maenhaut, Willy" uniqKey="Maenhaut W" first="Willy" last="Maenhaut">Willy Maenhaut</name><name sortKey="Szmigielski, Rafal" sort="Szmigielski, Rafal" uniqKey="Szmigielski R" first="Rafal" last="Szmigielski">Rafal Szmigielski</name><name sortKey="Vermeylen, Reinhilde" sort="Vermeylen, Reinhilde" uniqKey="Vermeylen R" first="Reinhilde" last="Vermeylen">Reinhilde Vermeylen</name></country><country name="France"><region name="Provence-Alpes-Côte d'Azur"><name sortKey="Yasmeen, Farhat" sort="Yasmeen, Farhat" uniqKey="Yasmeen F" first="Farhat" last="Yasmeen">Farhat Yasmeen</name></region></country><country name="Pologne"><noRegion><name sortKey="Szmigielski, Rafal" sort="Szmigielski, Rafal" uniqKey="Szmigielski R" first="Rafal" last="Szmigielski">Rafal Szmigielski</name></noRegion></country><country name="États-Unis"><noRegion><name sortKey="Surratt, Jason D" sort="Surratt, Jason D" uniqKey="Surratt J" first="Jason D." last="Surratt">Jason D. Surratt</name></noRegion><name sortKey="Chan, Arthur W H" sort="Chan, Arthur W H" uniqKey="Chan A" first="Arthur W. H." last="Chan">Arthur W. H. Chan</name><name sortKey="Chan, Arthur W H" sort="Chan, Arthur W H" uniqKey="Chan A" first="Arthur W. H." last="Chan">Arthur W. H. Chan</name><name sortKey="Seinfeld, John H" sort="Seinfeld, John H" uniqKey="Seinfeld J" first="John H." last="Seinfeld">John H. Seinfeld</name><name sortKey="Seinfeld, John H" sort="Seinfeld, John H" uniqKey="Seinfeld J" first="John H." last="Seinfeld">John H. Seinfeld</name><name sortKey="Surratt, Jason D" sort="Surratt, Jason D" uniqKey="Surratt J" first="Jason D." last="Surratt">Jason D. Surratt</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Amerique/explor/CaltechV1/Data/France/Analysis
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000007 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/France/Analysis/biblio.hfd -nk 000007 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Wicri/Amerique
|area= CaltechV1
|flux= France
|étape= Analysis
|type= RBID
|clé= ISTEX:2E7DC6F7F66D79FF4FFD8C32B9F78A48EEE0687B
|texte= Mass spectrometric characterization of isomeric terpenoic acids from the oxidation of α‐pinene, β‐pinene, d‐limonene, and Δ3‐carene in fine forest aerosol
}}
| This area was generated with Dilib version V0.6.32. |  |